Dimethylalkoxygallane incorporating a donor-functionalised alkoxide: the monomeric gas-phase structure.

نویسندگان

  • Caroline E Knapp
  • Claire J Carmalt
  • Paul F McMillan
  • Derek A Wann
  • Heather E Robertson
  • David W H Rankin
چکیده

The structure of the vapour produced upon heating the dimethylalkoxygallane [Me(2)GaOCH(2)CH(2)NMe(2)](2) has been studied by gas-phase electron diffraction and ab initio molecular orbital calculations; only the monomeric form [Me(2)GaOCH(2)CH(2)NMe(2)] is observed in the vapour, with the nitrogen atom forming a dative bond with the metal centre.

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عنوان ژورنال:
  • Dalton transactions

دوره 48  شماره 

صفحات  -

تاریخ انتشار 2008